Colloidal inorganic nano- and microparticles for passive daytime radiative cooling

Compared to traditional cooling systems, radiative cooling (RC) is a promising cooling strategy in terms of reducing energy consumption enormously and avoiding severe environmental issues. Radiative cooling materials (RCMs) reduce the temperature of objects without using an external energy supply by dissipating thermal energy via infrared (IR) radiation into the cold outer space through the atmospheric window. Therefore, RC has a great potential for various applications, such as energy-saving buildings, vehicles, water harvesting, solar cells, and personal thermal management. Herein, we review the recent progress in the applications of inorganic nanoparticles (NPs) and microparticles (MPs) as RCMs and provide insights for further development of RC technology. Particle-based RCMs have tremendous potential owing to the ease of engineering their optical and physical properties, as well as processibility for facile, inexpensive, and large area deposition. The optical and physical properties of inorganic NPs and MPs can be tuned easily by changing their size, shape, composition, and crystals structures. This feature allows particle-based RCMs to fulfill requirements pertaining to passive daytime radiative cooling (PDRC), which requires high reflectivity in the solar spectrum and high emissivity within the atmospheric window. By adjusting the structures and compositions of colloidal …